| Matchday | Date | Time | Game | Score | Rank |
|---|---|---|---|---|---|
| 1 | 09-08-2020 | 18:15 | KV Mechelen - RSCA | 2-2 | 6 |
| 2 | 16-08-2020 | 18:15 | RSCA - Sint-Truiden VV | 3-1 | 4 |
| 3 | 23-08-2020 | 18:15 | RSCA - Royal Excel Mouscron | 1-1 | 5 |
| 4 | 28-08-2020 | 20:45 | KV Oostende - RSCA | 2-2 | 8 |
| 5 | 13-09-2020 | 13:30 | RSCA - Cercle Brugge | 2-0 | 6 |
| 6 | 19-09-2020 | 20:45 | Waasland-Beveren - RSCA | 2-4 | 5 |
| 7 | 27-09-2020 | 16:00 | RSCA - KAS Eupen | 1-1 | 5 |
| 8 | 04-10-2020 | 13:30 | Club Brugge - RSCA | 3-0 | 7 |
| 9 | 18-10-2020 | 20:30 | RSCA - Oud Heverlee Leuven | 2-2 | 9 |
| 10 | 25-10-2020 | 20:45 | KV Kortrijk - RSCA | 1-3 | 7 |
| 11 | 01-11-2020 | 13:30 | RSCA - Royal Antwerp | 1-0 | 6 |
| 12 | 08-11-2020 | 18:15 | KAA Gent - RSCA | 1-1 | 7 |
| 13 | 22-11-2020 | 13:30 | Beerschot AC - RSCA | 2-1 | 7 |
| 14 | 29-11-2020 | 18:15 | RSCA - Standard de Liège | 0-0 | 7 |
| 15 | 04-12-2020 | 20:45 | Zulte Waregem - RSCA | 2-2 | 7 |
| 16 | 11-12-2020 | 20:45 | RSCA - KRC Genk | 1-0 | 6 |
| 17 | 18-12-2020 | 20:45 | Charleroi - RSCA | 1-0 | 5 |
| 18 | 15-12-2020 | 21:00 | RSCA - KV Oostende | 2-1 | 5 |
| 19 | 27-12-2020 | 18:15 | RSCA - Beerschot AC | 2-0 | 4 |
| 20 | 15-01-2021 | 20:45 | KAS Eupen - RSCA | 2-0 | 7 |
| 21 | 22-01-2021 | 20:45 | RSCA - Waasland-Beveren | 0-0 | 5 |
| 22 | 26-01-2021 | 21:00 | Royal Excel Mouscron - RSCA | 1-1 | 5 |
| 23 | 31-01-2021 | 18:15 | RSCA - KAA Gent | 0-0 | 5 |
| 24 | 07-02-2021 | 18:15 | KRC Genk - RSCA | 1-2 | 4 |
| 25 | 19-01-2021 | 21:00 | RSCA - Charleroi | 3-0 | 5 |
| 26 | 14-02-2021 | 20:45 | Cercle Brugge - RSCA | 0-0 | 5 |
| 27 | 21-02-2021 | 13:30 | RSCA - KV Kortrijk | 0-2 | 5 |
| 28 | 28-02-2021 | 13:30 | Standard de Liège - RSCA | - | - |
| 29 | 07-03-2021 | 18:15 | RSCA - KV Mechelen | - | - |
| 30 | 10-01-2021 | 18:15 | Oud Heverlee Leuven - RSCA | 1-0 | 5 |
| 31 | 21-03-2021 | 18:15 | RSCA - Zulte Waregem | - | - |
| 32 | 05-04-2021 | 18:15 | Royal Antwerp - RSCA | - | - |
| 33 | 12-04-2021 | - | RSCA - Club Brugge | - | - |
| 34 | 18-04-2021 | - | Sint-Truiden VV - RSCA | - | - |
| Matchday | Date | Time | Game | Score |
|---|---|---|---|---|
| 1/16 Final | 03-02-2021 | 21:15 | Club de Liège - RSCA | 0-2 |
| 1/8 Final | 11-02-2021 | 20:45 | Royale Union Saint-Gilloise - RSCA | 0-5 |
| 1/4 Final | 03-03-2021 | 20:45 | RSCA - Cercle Brugge | - |
| Date | Time | Game | Score |
|---|---|---|---|
| 04-07-2020 | 12:00 | RSCA - Royal Charleroi Sporting Club | 0-1 |
| 11-07-2020 | 13:00 | RSCA - K. ST.-TRUIDENSE V.V. | 3-0 |
| 18-07-2020 | 15:30 | Association sportive de Saint-Étienne - RSCA | 1-3 |
| 25-07-2020 | 15:00 | RSCA - FC Nantes | 0-0 |
| 01-08-2020 | 10:30 | RSCA - Racing White Daring Molenbeek | 2-1 |
| 01-08-2020 | 15:00 | Lille OSC - RSCA | 2-0 |
| 09-08-2020 | 10:30 | RSCA - Lommel SK | 3-0 |
| 04-09-2020 | 14:00 | TSV Bayer 04 Leverkusen - RSCA | 1-1 |
| 24-10-2020 | 11:30 | RSCA - Royal Charleroi Sporting Club | 0-0 |
| 13-11-2020 | 13:00 | RSCA - Racing club de Lens | 1-3 |
| 14-11-2020 | 12:00 | Royal Charleroi Sporting Club - RSCA | 0-2 |
| 30-11-2020 | 11:30 | RSCA - Racing White Daring Molenbeek | 6-1 |
| 12-12-2020 | 11:00 | KVC Westerlo - RSCA | 1-3 |
| 09-01-2021 | 14:00 | SK Lierse - RSCA | 2-1 |
| 16-01-2021 | 14:00 | RSCA - Royale Union Saint-Gilloise | 0-1 |
| 15-02-2021 | 14:00 | Oud-Heverlee Leuven - RSCA | 1-5 |
| 22-02-2021 | 11:30 | RSCA - Racing White Daring Molenbeek | 3-1 |
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